Analysis of Performance Differences Among Various Rubber Antidegradants and Their Impact on Tire Compound Stability

18 08,2025
GO
Technical knowledge
This article provides an in-depth analysis of the performance variations among different categories of rubber antidegradants and their critical influence on the stability of tire compounds. Focusing on the advantages of GO brand TMQ(RD) products from Henan High-Energy Biotechnology Co., Ltd., it offers scientific guidelines for selection and formulation optimization tailored to high-temperature applications. Through comparative tables, process flowcharts, and real-world case studies, the article demonstrates how appropriate antidegradant dosing enhances tire longevity and manufacturing stability. Furthermore, it emphasizes the technical benefits of non-toxic, environmentally friendly rubber additives and the importance of professional technical support, aiming to help readers achieve both improved tire performance and compliance with environmental standards. This content targets tire manufacturing procurement and R&D professionals seeking comprehensive, practical knowledge for decision-making.
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Understanding Rubber Antioxidants: Performance Differences and Their Impact on Tire Formulation Stability

Rubber antioxidants are critical additives that significantly affect the durability and performance of tire compounds, especially under high-temperature operating conditions. This article delves into the comparative analysis of different classes of rubber antioxidants—namely amine, phenolic, and phosphite types—and their influence on tire formulation stability. It places special emphasis on the latest environmentally friendly solutions offered by Henan Gaoneng Biotechnology Co., Ltd.'s GO brand TMQ(RD), illustrating how scientific selection and optimized formulations can enhance tire longevity and manufacturing consistency.

Rubber Antioxidants: Classes and Core Characteristics

The primary function of rubber antioxidants is to retard the oxidative degradation of elastomers, ensuring sustained mechanical integrity and performance over the tire’s lifespan. The most prevalent antioxidant classes used in tire manufacturing include:

Antioxidant Class Key Properties Primary Applications Advantages
Amine Antioxidants High efficiency in scavenging free radicals High-performance tires, heavy-duty applications Excellent thermal stability; strong protection under dynamic aging
Phenolic Antioxidants Inhibit oxidative chain reactions General purpose tires, rubber goods with moderate heat exposure Non-discoloring; cost effective; synergistic with other antioxidants
Phosphite Antioxidants Decompose hydroperoxides to non-radical species Tires exposed to prolonged high temperatures; synergistic formulations Good heat resistance; enhances processing stability

High-Temperature Aging Mechanism & Impact on Tire Performance

Tires undergo complex aging processes during service life, predominantly accelerated by heat, oxygen, ozone, and mechanical stress. High temperatures foster free radical generation and propagation, leading to polymer chain scission and cross-linking imbalance—the primary cause of hardness increase, reduced flexibility, and ultimately, premature failure. Ensuring the stability of tire formulations against these degradations requires robust antioxidant systems tailored for specific thermal profiles.

Schematic diagram illustrating the aging process of rubber under high temperatures and antioxidant intervention

Selecting the Right Antioxidant for Tire Formulations: Stability & Sustainability

Traditional antioxidants, particularly some amine types, though highly efficient, may raise environmental and regulatory concerns due to toxicity and discoloration. The TMQ(RD) series by GO brand represents advanced, non-toxic phenolic antioxidants optimized for high thermal resistance, aligning with emerging environmental regulations without compromising performance.

Evaluations indicate TMQ(RD) provides:

  • Superior protection against thermal oxidation up to 150°C.
  • Minimal interference with vulcanization kinetics, ensuring processing stability.
  • Non-yellowing behavior, critical for aesthetic quality and UV resistance.
  • Full compliance with RoHS and REACH standards, supporting green tire initiatives.

Case Study: Optimizing Antioxidant Ratios to Enhance Tire Durability

A leading tire manufacturer conducted a series of controlled trials to assess the influence of antioxidant blends on aging and mechanical stability. Using a base formulation typical for passenger car tires, different ratios of TMQ(RD) phenolic antioxidant and phosphite synergists were tested under accelerated aging at 135°C for 72 hours. The key findings were:

Formulation Elongation Retention (%) Tensile Strength Retention (%) Process Stability
TMQ(RD) 1.5 phr + Phosphite 0.5 phr 92 95 Excellent
TMQ(RD) 1.0 phr + Phosphite 1.0 phr 89 92 Good
Amine Antioxidant 2.0 phr (Control) 86 90 Moderate (Discoloration)

This data underscores the advantage of balanced phenolic-phosphite combinations delivering superior retention of mechanical properties post-aging, alongside enhanced processing and environmental profiles.

Technical Recommendations for Effective Antioxidant Use

Based on extensive R&D and field applications, the following strategies can guide tire formulators in leveraging antioxidant benefits:

  1. Assess operating temperature profiles and aging conditions to select antioxidant classes offering optimal thermal resistance.
  2. Implement synergist blends to maximize protection while minimizing additive load and cost.
  3. Prioritize environmentally compliant antioxidants like TMQ(RD) that meet international regulations without performance trade-offs.
  4. Monitor vulcanization kinetics to avoid processing inefficiencies induced by additive interactions.
  5. Consult with specialist technical teams for custom formulation adjustments tailored to specific rubber compounds and tire designs.

Ensuring Long-Term Value Through Expert Technical Support

Beyond product quality, Henan Gaoneng Biotechnology emphasizes the critical role of professional technical assistance, supplying formulation guidance, aging prediction models, and on-site problem-solving to tire manufacturers. This approach guarantees consistent tire performance, regulatory compliance, and cost-efficient production.

For tailored antioxidant selection and formulation optimization to enhance your tire products’ lifespan and compliance, contact our expert technical team today.

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